To load a language pair which isn't part of the config, all you need to do is specify the language code as pairs. You can find the valid pairs in Homepage section of Dataset Description: http://opus.nlpl.eu/PHP.php E.g.
dataset = load_dataset("php", lang1="it", lang2="pl")
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Here are some examples of questions and facts:
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Thanks to @abhishekkrthakur for adding this dataset.